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69. Iron-Catalyzed Cross-Coupling of Diarylzinc Reagents with gem-Difluoropropargyl Bromide  

An, Lun  Tong, Feifei  Zhang, Xingang*

Acta Chim. Sinica 2019, 76, 977—982 

( Invitated paper for Acta Chimica Sinica)



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68. Fluoroalkylation-Borylation of Alkynes: An Efficient Method To Obtain (Z)Tri- and 

Tetrasubstituted Fluoroalkylated Alkenylboronates 

Wen-Hao Guo, Hai-Yang Zhao, Zhi-Ji Luo, Shu Zhang, and Xingang Zhang* 

ACS Catal. 2019, 9, 38-43 



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67. Palladium-catalyzed direct allylation of fluorinated benzothiadiazoles with allyl chlorides  

Jing Wang , Yan-Bo Yu , Xingang Zhang *

Tetrahedron. 2018, 74, 6329 - 6334. 

( Invitated paper for special issue on Organo Fluorine Chemistry )  



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66. Nickel-Catalyzed Difluoroalkylation of (Hetero)aryl Bromides with Unactivated 1-Bromo-1,1-difluoroalkanes  

Xu He, Xing Gao, and Xingang Zhang*

Chin. J. Chem. 2018, 36, 10591062.

Invited paper, Dedicated to professor Xiyan Lu on the occasion of his 90th birthday



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65. Transition-Metal (Cu, Pd, Ni)-Catalyzed Difluoroalkylation via Cross-Coupling with Difluoroalkyl Halides  

Zhang Feng, Yu-Lan Xiao and Xingang Zhang*

Acc. Chem. Res., 2018, 51, 2264



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64. Highly Selective Pd-Catalyzed Direct C-F Bond Arylation of Simple Polyfluoroarenes

Zhi-Ji Luo, Hai-Yang Zhao, and Xingang Zhang* 

Org. Lett., 2018, 20, 2543-2546


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63. A Bulky Diamine Ligand Promoted Cross-Coupling with Difluoroalkyl Bromides via Iron Catalysis

Lun An, Yu-Lan Xiao, Shu Zhang and Xingang Zhang*

Angew. Chem. Int. Ed. 2018, 57, 6921-6925


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62. Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel

Chang Xu, Wen-Hao Guo, Xu He, Ying-Long Guo, Xue-Ying Zhang, and Xingang Zhang*

Nat. Commun., 2018, 9, 1170

(A story behind this paper: )

(This paper was chosen to feature within, under Fluorine for celebrating the International Year of the Periodic Table of Chemical Elements from across Nature and the Nature-branded journals)

see: https://www.nature.com/immersive/d42859-019-00001-7/index.html


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61. Bromotrifluoromethane: A Useful Reagent for Hydrotrifluoromethylation of Alkenes and Alkynes

Yu-Yan Ren, Xing Zheng,* and Xingang Zhang*

Synlett2018, 29, 1028-1032

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60. Nickel-Catalyzed Difluoromethylation of Arylboronic Acids with Bromodifluoromethane

Xia-Ping Fu, Yu-Lan Xiao, and Xingang Zhang*

Chin. J. Chem.201836, 143-146

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