49. Copper-Catalyzed Direct Propargylation of Polyfluoroarene With Secondary Propargyl Phosphates

Yan-Bo Yu, Zhi-Ji Luo, and Xingang Zhang^*

Org.Lett. 2016, 18, 3302

48.Palladium-catalyzed phosphonyldifluoromethylation of alkenes with bromodifluoromethylphosphonate

Zhang Feng, Yu-Lan Xiao and Xingang Zhang*

Org. Chem. Front., 2016, 3, 466–469

47.Nickel-Catalyzed Difluoroalkylation of (Hetero)Arylborons with Unactivated 1-Bromo-1,1-difluoroalkanes

Yu-Lan Xiao+, Qiao-Qiao Min+, Chang Xu, Ruo-Wen Wang, and Xingang Zhang*

Angew. Chem. Int. Ed. 2016, 55, 5873-5841

(This paper was highlighted in Synthfacts, 2016, 55, 5837-5841 )

46.Access to Difluoromethylated Arenes by Pd-Catalyzed Reaction of Arylboronic Acids with Bromodifluoroacetate

Zhang Feng, Qiao-Qiao Min, and Xingang Zhang

Org. Lett. 2016, 18, 44-47

45.Pd-Catalyzed gem-Difluoroallylation of Arylboronic Acids withγ,γ-Difluoroallylic Acetates

Bo Zhang and Xingang Zhang^*

Chem. Commun. 2016, 52, 1238-1241

44.Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides 

Xuefei Li,Zhang Feng,Zhong-Xing Jiang*,and Xingang Zhang*

Org. Lett., 2015, 17 (22), 5570–5573

43.Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives 

Ji-Wei Gu and Xingang Zhang*

Org. Lett., 2015, 17 (21), 5384–5387

42.Palladium-Catalyzed Heck-Type Difluoroalkylation of Alkenes with Functionalized Difluoromethyl Bromides.

Feng Zhang, Qiao-Qiao Min, Xingang Zhang*

Synthesis. 2015, 47 (19), 2912-2923

41.Palladium-Catalyzed Direct Thienylation of Monobromide-Substituted Difluorinated Benzothiadiazoles for Organic Photovoltaics.

Qiang Pan, Chun-Yang He, Shiqing Han*, Xingang Zhang*

Synlett. 2015, 26 (15), 2175-2179

40. Rhodium-Catalyzed ortho-Selective CF Bond Borylation of Polyfluoroarenes with BpinBpin 

Wen Haoguo, Qiao-Qiao Min, Ji-Wei Gu and Xingang Zhang*

Angew. Chem. Int. Ed. 2015, 54, 9075-9078 .