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76.Copper-Catalyzed Highly Enantioselective Difluoroalkylation of Secondary Propargyl Sulfonates with Difluoroenoxysilanes

Xing Gao, Ran Cheng, Yu-Lan Xiao, Xiao-Long Wan, and Xingang Zhang*

Chem. 201952987-2999

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75.Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes

Xia-Ping Fu, Xiao-Song Xue, Xue-Ying Zhang, Yu-Lan Xiao, Shu Zhang, Yin-Long Guo, Xuebing Leng, 

Kendall N. Houk * and Xingang Zhang *

Nat. Chem. 2019, 11948956 

(A story behind this paper: )(after the paper



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74.Nickel-Catalyzed Difluoroalkylation-Alkylation of Enamides 

Chang Xu, Zhi-Fang Yang, Lun An, and Xingang Zhang*,

ACS Catal. 2019, 9, 8224-8229


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73.Palladium-catalyzed cross-coupling of unactivated alkylzinc reagents with 2-bromo-3,3,3-trifluoropropene and its application in the synthesis of fluorinated amino acids

Yue-Guang Lou, An-Jun Wang, Liang Zhao, Lin-Feng He, Xiao-Fei Li, Chun-Yang He * and Xingang Zhang *

Chem. Commun. 2019, 55, 3705-3708

(This paper was highlighted by Chemical Synfacts, 2019, 55, 3705 )





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72. Nickel-Catalyzed Carbonylation of Difluoroalkyl Bromides with Arylboronic Acids 

Hai-Yang Zhao, Xing Gao, Shu Zhang, and Xingang Zhang* 

Org. Lett.201921, 1031–1036


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71.Nickel-Catalyzed Difluoromethylation of (Hetero)aryl Bromides with BrCF2H  

Xing Gao, Xu He and Xingang Zhang*

Chin. J. Org. Chem. 2019, 39, 215-222

(Invited paper, Dedicated to professor Qing-Yun Chen on the occasion of his 90th birthday )


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70. Ni-Catalyzed Defluorination for the Synthesis of gem-Difluoro-1,3-dienes and Their [4+2] Cycloaddition Reaction  
 Minqi Zhou, Jian Zhang, Xing-Guo Zhang* and Xingang Zhang*

Org.Lett201921, 671- 674



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69. Fluoroalkylation-Borylation of Alkynes: An Efficient Method To Obtain (Z)‑Tri- and Tetrasubstituted Fluoroalkylated Alkenylboronates

Wen-Hao Guo, Hai-Yang Zhao, Zhi-Ji Luo, Shu Zhang, and Xingang Zhang*  

ACS Catal. 2019, 9, 38-43 



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