91.Regio- and enantioselective umpolung gemdifluoroallylation of hydrazones via palladium catalysis enabled by N-heterocyclic carbene ligand

Shuai Huang, Fei-Fei Tong, Da-Chang Bai, Gao-Peng Zhang, Yang-Jie Jiang, Bo Zhang, Xuebing Leng, Ying-Long Guo, Xiao-Long Wan, Xingang Zhang*, Chang-Hua Ding* & Xue-Long Hou*

Nat. Commun., 2021, 12, 6551.

90.Visible-Light-Induced Palladium-Catalyzed Selective Defluoroarylation of Trifluoromethylarenes with Arylboronic Acids

Yun-Cheng Luo, Fei-Fei Tong, Yanxia Zhang, Chun-Yang He, and Xingang Zhang*

J. Am. Chem. Soc. 2021, 143, 13971-13979.

（This paper was highlighted by Synfacts, 2021, 17, 1230 ）

89.Highly γ-Selective Arylation and Carbonylative Arylation of 3-Bromo-3,3-difluoropropene via Nickel Catalysis

Ran Cheng, Yueqian Sang, Xing Gao, Shu Zhang, Xiao-Song Xue*, and Xingang Zhang* 

Angew. Chem. Int. Ed. 2021, 60, 12386-12391.

(Hot Paper)

88. Using Chlorotrifluoroethane for Tifluoroethylation of (Hetero)Aryl Bromides and Chlorides via Nickel Catalysis

Xuefei Li, Xing Gao, Chun-Yang He, Xingang Zhang*

Org. Lett. 2021, 23, 1400−1405.

87. Access to α,α-Difluoro-γ-amino Acids by Nickel-Catalyzed Reductive Aryldifluoroacetylation of N-Vinylacetamide

Qing-Wei Zhao, Zhi-Fang Yang, Xia-Ping Fu, Xingang Zhang*

Synlett 2021, 32, 1565-1569.

（Invited paper for the Cluster Modern Nickel-Catalyzed Reactions）

86.Nickel-Catalyzed Four-Component Carbocarbonylation of Alkenes under 1 atm of CO

Minqi Zhou^†, Hai-Yang Zhao^†, Shu Zhang, Yanxia Zhang, and Xingang Zhang* 

J. Am. Chem. Soc. 2020, 142, 42, 18191–18199.

(Minqi Zhou and Hai-Yang Zhao contributed equally.)

（This paper was highlighted by Synfacts, 2021, 17, 0109 ）

85. Decarboxylative and Deaminative Alkylation of Difluoroenoxysilanes via Photoredox Catalysis: A General Method for Site-Selective Synthesis of Difluoroalkylated Alkanes  

Heng Song, Ran Cheng, Qiao-Qiao Min, Xingang Zhang*

Org. Lett. 2020, 22, 7747-7751.

（This paper was highlighted by Synfacts, 2020, 16, 1478 ）

84. Nickel-catalyzed regioselective coupling reaction of 3,3,3-trifluoropropene with arylzinc reagents  

Ran Cheng, Chang Xu, Xingang Zhang*

Chin. J. Org. Chem. 2020, 40, 3307-3313

(Invited paper)

83.Copper-Catalyzed Enantioselective Trifluoromethylthiolation of Secondary Propargyl Sulfonates

Xing Gao, Yu-Lan Xiao, Shu Zhang, Jian Wu, and Xingang Zhang*

CCS Chem. 2020, 2, 1463-1471. 

82.Nickel-Catalyzed Dicarbofunctionalization of Alkenes

Yun-Cheng Luo, Chang Xu, Xingang Zhang* 

Chin. J. Chem. 2020, 38, 1371-1394.