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67. Palladium-catalyzed direct allylation of fluorinated benzothiadiazoles with allyl chlorides  

Jing Wang , Yan-Bo Yu , Xingang Zhang *

Tetrahedron. 2018, 74, 6329 - 6334. 

(Invitated paper for special issue on Organo Fluorine Chemistry )  





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66. Nickel-Catalyzed Difluoroalkylation of (Hetero)aryl Bromides with Unactivated 1-Bromo-1,1-difluoroalkanes  

Xu He, Xing Gao, and Xingang Zhang*

Chin. J. Chem. 2018, 36, 10591062.

(Invited paper, Dedicated to professor Xiyan Lu on the occasion of his 90th birthday )


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65. Transition-Metal (Cu, Pd, Ni)-Catalyzed Difluoroalkylation via Cross-Coupling with Difluoroalkyl Halides  

Zhang Feng, Yu-Lan Xiao and Xingang Zhang*

Acc. Chem. Res., 2018, 51, 2264-2278


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64. Highly Selective Pd-Catalyzed Direct C-F Bond Arylation of Simple Polyfluoroarenes 

Zhi-Ji Luo, Hai-Yang Zhao, and Xingang Zhang*

Org. Lett., 2018, 20, 2543-2546


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63. A Bulky Diamine Ligand Promoted Cross-Coupling with Difluoroalkyl Bromides via Iron Catalysis

Lun An, Yu-Lan Xiao, Shu Zhang and Xingang Zhang*

Angew. Chem. Int. Ed. 2018, 57, 6921-6925 

(This paper was highlighted by Synthfacts, 2018, 14, 0850 )

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62. Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel

Chang Xu, Wen-Hao Guo, Xu He, Ying-Long Guo, Xue-Ying Zhang, and Xingang Zhang*

Nat. Commun., 2018, 9, 1170

(A story behind this paper: )(This paper was chosen to feature within, under Fluorine for celebrating the International Year of the Periodic Table of Chemical Elements from across Nature and the Nature-branded journals)




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61. Bromotrifluoromethane: A Useful Reagent for Hydrotrifluoromethylation of Alkenes and Alkynes

Yu-Yan Ren, Xing Zheng,* and Xingang Zhang*

Synlett, 2018, 29, 1028-1032

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60. Nickel-Catalyzed Difluoromethylation of Arylboronic Acids with Bromodifluoromethane

Xia-Ping Fu, Yu-Lan Xiao, and Xingang Zhang*

Chin. J. Chem., 2018, 36, 143-146

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59. Copper-Catalyzed Highly Stereospecific Trifluoromethylation and Difluoroalkylation of Secondary Propargyl Sulfonates 

Xing Gao, Yu-Lan Xiao, Xiaolong Wan, and Xingang Zhang*

 Angew. Chem. Int. Ed. 2018, 57, 3187-3191

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58. Palladium-Catalyzed Heck-Type Reaction of Secondary Trifluoromethylated Alkyl Bromides 

Tao Fan, Wei-Dong Meng and Xingang Zhang*

Beilstein J. Org. Chem. 2017, 13, 2610


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