74.Nickel-Catalyzed Difluoroalkylation-Alkylation of Enamides 

Chang Xu, Zhi-Fang Yang, Lun An, and Xingang Zhang*^,

^{ACS Catal. 2019, 9, 8224-8229}

72. Nickel-Catalyzed Carbonylation of Difluoroalkyl Bromides with Arylboronic Acids 

Hai-Yang Zhao, Xing Gao, Shu Zhang, and Xingang Zhang* 

Org. Lett., 2019, 21, 1031–1036

71.Nickel-Catalyzed Difluoromethylation of (Hetero)aryl Bromides with BrCF2H  

Xing Gao, Xu He and Xingang Zhang*

Chin. J. Org. Chem. 2019, 39, 215-222

(Invited paper, Dedicated to professor Qing-Yun Chen on the occasion of his 90th birthday )

70. Ni-Catalyzed Defluorination for the Synthesis of gem-Difluoro-1,3-dienes and Their [4+2] Cycloaddition Reaction  
 Minqi Zhou, Jian Zhang, Xing-Guo Zhang* and Xingang Zhang*

Org.Lett. 2019, 21, 671- 674

69. Fluoroalkylation-Borylation of Alkynes: An Efficient Method To Obtain (Z)‑Tri- and Tetrasubstituted Fluoroalkylated Alkenylboronates

Wen-Hao Guo, Hai-Yang Zhao, Zhi-Ji Luo, Shu Zhang, and Xingang Zhang*  

ACS Catal. 2019, 9, 38-43 

68. Iron-Catalyzed Cross-Coupling of Diarylzinc Reagents with gem-Difluoropropargyl Bromide    

An, Lun  Tong, Feifei  Zhang, Xingang*

Acta Chim. Sinica 2018, 76, 977—982 

(Invitated paper for Acta Chimica Sinica )

66. Nickel-Catalyzed Difluoroalkylation of (Hetero)aryl Bromides with Unactivated 1-Bromo-1,1-difluoroalkanes  

Xu He, Xing Gao, and Xingang Zhang*

Chin. J. Chem. 2018, 36, 1059－1062.

(Invited paper, Dedicated to professor Xiyan Lu on the occasion of his 90th birthday )

65. Transition-Metal (Cu, Pd, Ni)-Catalyzed Difluoroalkylation via Cross-Coupling with Difluoroalkyl Halides  

Zhang Feng, Yu-Lan Xiao and Xingang Zhang*

Acc. Chem. Res., 2018, 51, 2264-2278

63. A Bulky Diamine Ligand Promoted Cross-Coupling with Difluoroalkyl Bromides via Iron Catalysis

Lun An, Yu-Lan Xiao, Shu Zhang and Xingang Zhang*

Angew. Chem. Int. Ed. 2018, 57, 6921-6925 

(This paper was highlighted by Synthfacts, 2018, 14, 0850 )

62. Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel

Chang Xu, Wen-Hao Guo, Xu He, Ying-Long Guo, Xue-Ying Zhang, and Xingang Zhang*

Nat. Commun., 2018, 9, 1170

(A story behind this paper: )(This paper was chosen to feature within, under Fluorine for celebrating the International Year of the Periodic Table of Chemical Elements from across Nature and the Nature-branded journals)