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35. Heteroaryldifluoromethylation of Organoborons Catalyzed by Palladium:
Facile Access to Aryl(Heteroaryl)difluoromethanes 
Yu-Lan Xiao, Bo Zhang, Zhang Feng, and Xingang
Zhang*
Org. Lett. 2014, 16, 4822−4825.
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34. Synthesis of α,α-Difluoromethylene Alkynes by Palladium-Catalyzed
gem-Difluoropropargylation of Aryl and Alkenyl Boron Reagents 
(This
paper was highlighted in Synfacts, 2014, 10, 1303 )
Yan-Bo Yu,
Guo-Zhen He and Xingang Zhang*
Angew. Chem. Int. Ed. 2014, 53, 10457 –10461
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33. Nickel-Catalyzed Cross-Coupling of Functionalized Difluoromethyl
Bromides and Chlorides with Aryl Boronic Acids: A General Method for
Difluoroalkylated Arenes
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25 )
Yu-Lan Xiao,Wen-Hao Guo, Guo-Zhen He, Qiang
Pan and Xingang
Zhang*.
Angew. Chem. Int. Ed. 2014, 53，9909-9913
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32. Pd-catalyzed aerobic direct olefination of
polyfluoroarenes 
Chun-Yang
He, Feng-Ling Qing and Xingang Zhang*.
Tetrahedron Lett., 2014, 55, 2962-2964
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31. Direct Olefination of Fluorinated Benzothiadiazoles: A New Entry to
Optoelectronic Materials 
Yu-Lan
Xiao,Bo Zhang,Chun-Yang He and Xingang Zhang*.
Chem.
Eur. J., 2014, 20,
4532-4536
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30. Selective thienylation of
fluorinated benzothiadiazoles and benzotriazoles for organic
photovoltaics 
Chun-Yang He, Cai-Zhi Wu, Yan-Lin Zhu and Xingang
Zhang*.
Chem. Sci., 2014, 5, 1317-1321
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29. Direct (Het)Arylation
of Fluorinated Benzothiadiazoles and Benzotriazole with (Het)Aryl
Iodides 
Chun-Yang
He, Cai-Zhi Wu, Feng-Ling Qing and Xingang Zhang*.
J. Org.
Chem., 2014, 79,
1712-1718
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28. Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate
with iodo/bromo-aryl triazenes 
Zhang Feng, Yu-Lan Xiao and Xingang Zhang*
Org. Chem.
Front., 2014, 1, 113-116
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27. Palladium-Catalyzed
Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of
Aryldifluoromethylated Phosphonates and Carboxylic Acid
Derivatives 
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25  )
Zhang Feng, Qiao-Qiao Min, Yu-Lan Xiao, Bo Zhan and Xingang
Zhang*
Angew. Chem. Int. Ed. 2014, 53, 1669 –1673
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26. Pd-catalyzed
cross-coupling of polyfluoroarenes with cyclic vinyl triflates 
YanBo Yu, Zhen Wang and Xingang Zhang*
Sci China
Chem, 2014, 57, 276-281
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