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31. Direct Olefination of Fluorinated Benzothiadiazoles: A New Entry to
Optoelectronic Materials 
Yu-Lan
Xiao,Bo Zhang,Chun-Yang He and Xingang Zhang*.
Chem.
Eur. J., 2014, 20,
4532-4536
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30. Selective thienylation of
fluorinated benzothiadiazoles and benzotriazoles for organic
photovoltaics 
Chun-Yang He, Cai-Zhi Wu, Yan-Lin Zhu and Xingang
Zhang*.
Chem. Sci., 2014, 5, 1317-1321
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29. Direct (Het)Arylation
of Fluorinated Benzothiadiazoles and Benzotriazole with (Het)Aryl
Iodides 
Chun-Yang
He, Cai-Zhi Wu, Feng-Ling Qing and Xingang Zhang*.
J. Org.
Chem., 2014, 79,
1712-1718
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28. Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate
with iodo/bromo-aryl triazenes 
Zhang Feng, Yu-Lan Xiao and Xingang Zhang*
Org. Chem.
Front., 2014, 1, 113-116
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27. Palladium-Catalyzed
Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of
Aryldifluoromethylated Phosphonates and Carboxylic Acid
Derivatives 
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25  )
Zhang Feng, Qiao-Qiao Min, Yu-Lan Xiao, Bo Zhan and Xingang
Zhang*
Angew. Chem. Int. Ed. 2014, 53, 1669 –1673
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26. Pd-catalyzed
cross-coupling of polyfluoroarenes with cyclic vinyl triflates 
YanBo Yu, Zhen Wang and Xingang Zhang*
Sci China
Chem, 2014, 57, 276-281
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25. Highly Selective
gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes
Catalyzed by Palladium
Qiao-Qiao Min, Zengsheng Yin, Zhang Feng, Wen-Hao
Guo and Xingang Zhang*
J. Am. Chem. Soc.
2014, 136, 1230-1233
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24. Thioether-Promoted Direct Olefination
of Polyfluoroarenes Catalyzed by Palladium
Cai-Zhi Wu, Chun-Yang He, Yangen Huang and
Xingang Zhang*
Org. Lett., 2013, 15, 5233-5269
(This
paper was highlighted in Synfacts, 2014,
10, 0062  )
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23. Pd-Catalyzed Direct Arylation of
Nitro-(pentafluorosulfanyl)benzenes with Aryl Bromides
Chao Wang, Yan-Bo Yu, Shilu Fan, and Xingang
Zhang*
Org. Lett., 2013, 15,
5004–5007
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22. Nickel-Catalyzed ortho-Selective
Hydrodefluorination of N-Containing Heterocycle-Polyfluoroarenes
Yi He, Zhao Chen, Chun-Yang He, Xingang
Zhang*
Chin. J. Chem. 2013, 31,
873—877
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Copyright © 2012 Zhang Group, SIOC