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97. Highly Enantioselective Nickel-Catalyzed Dicarbofunctionalization of 3,3,3-Trifluoropropene

Yun-Ze Li, Na Rao, Lun An, Xiao-Long Wan, Yanxia Zhang, and Xingang Zhang*

Nat. Commun., 202213, 5539.


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96. 3,3-Difluoroallyl Sulfonium Salts: Practical and Bench-StableReagents for Highly Regioselective gem-Difluoroallylations

Xiao-Tian Feng, Jin-Xiu Ren, Xing Gao, Qiao-Qiao Min, and Xingang Zhang*

Angew. Chem. Int. Ed. 2022, e202210103.

DOI: 10.1002/anie.202210103.



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95. Nickel-catalyzed alkyl-arylation of 3,3,3-trifluoropropene

Chang Xu, Ming-Kuan Wang, Shu Zhang & Xingang Zhang*

Commun. Chem. 20225, 41.

DOI: 10.1038/s42004-022-00659-7.

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94. Coupling of Heteroaryl Halides with Chlorodifluoroacetamides and Chlorodifluoroacetate via Nickel Catalysis

Dawei Zhang, Xing Gao, Qiao-Qiao Min, Yucheng Gu, Guillaume Berthon, and Xingang Zhang*

Chem. Eur. J. 2022, 28e202200642

DOI: 10.1002/chem.202200642

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92. Palladium-Catalyzed Carbonylative Cross-Coupling of Difluoroalkyl Halides with Alkylboranes under 1 atm of CO

Hai-Yang Zhao,§ Minqi Zhou,§ and Xingang Zhang*

Org. Lett. 2021, 23, 23, 9106-9111.


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91.Regio- and enantioselective umpolung gemdifluoroallylation of hydrazones via palladium catalysis enabled by N-heterocyclic carbene ligand

Shuai Huang, Fei-Fei Tong, Da-Chang Bai, Gao-Peng Zhang, Yang-Jie Jiang, Bo Zhang, Xuebing Leng, Ying-Long Guo, Xiao-Long Wan, Xingang Zhang*, Chang-Hua Ding* & Xue-Long Hou*

Nat. Commun., 202112, 6551.



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85. Decarboxylative and Deaminative Alkylation of Difluoroenoxysilanes via Photoredox Catalysis: A General Method for Site-Selective Synthesis of Difluoroalkylated Alkanes  

Heng Song, Ran Cheng, Qiao-Qiao Min, Xingang Zhang*

Org. Lett. 2020, 22, 7747-7751.

(This paper was highlighted by Synfacts, 2020, 16, 1478 

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84. Nickel-catalyzed regioselective coupling reaction of 3,3,3-trifluoropropene with arylzinc reagents  

Ran Cheng, Chang Xu, Xingang Zhang*

ChinJOrgChem202040, 3307-3313

(Invited paper)

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79.Palladium Difluorocarbene Involved Catalytic Coupling with Terminal Alkynes

Xue-Ying Zhang, Xia-Ping Fu, Shu Zhang, Xingang Zhang*

CCS Chem. 2020, 2, 293–304.


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77.Nickel-Catalyzed Carbonylation of Secondary Trifluoromethylated, Difluoromethylated, and Nonfluorinated Aliphatic Electrophiles with Arylboronic Acids under 1 atm of CO

Ran Cheng, Hai-Yang Zhao, Shu Zhang, and Xingang Zhang*

ACS Catal. 2020, 10, 36-42

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