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109. Late-Stage gem-Difluoroallylation of Phenol in Bioactive Molecules and Peptides with 3,3-Difluoroallyl Sulfonium Salts

Minqi Zhou,Jin-Xiu Ren, Xiao-Tian Feng, Hai-Yang Zhao,b Xia-Ping Fu,b Qiao-Qiao Min and Xingang Zhang*

Chem. Sci. , 2024, 15, 2937-2945


Chem. Sci., 2024,15, 2937-2945
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108. Modular Diastereoselective Construction of Polysubstituted Cyclopentanes Enabled by Cobalt-Catalyzed Arylfluoroalkylation of Cyclopentenes

Ming-Kuan Wang, Yun-Cheng Luo, Hai-Yang Zhao, Yanxia Zhang, Dawei Zhang, and Xingang Zhang*

ACS Catal. 2023, 13, 14090–14102
DOI: 10.1021/acscatal.3c03578



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107.Copper-Catalyzed Highly Stereoselective Hydrodifluoroallylation ofCyclopropenes and Alkenyl Boronates with 3,3-Difluoroallyl SulfoniumSalts

Xing Gao, Xiaoxiao Ren,  Wei Deng,  and Xingang Zhang*

Chin. J. Chem. 2023, 41, 3521—3527

(Invited paper, Breaking Report)


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106. Fluorinated TEMPO: A New Redox-Active Catholyte Material for Aqueous Zn-Anode Hybrid Flow Batteries

Ling-Chao Yu, Yun-Cheng Luo, Wei Feng, Shu Zhang*, and Xingang Zhang*
J. Mater. Chem. A, 2023, 11, 18911-18921




Taking advantage of the unique fluorine effect, a new fluorinated TEMPO derivative achieves high cell voltage, improved cycle stability and excellent rate capability in aqueous redox flow batteries.

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105. Nickel-Catalyzed Selective C(sp2)-F bond Alkylation of Industrially Relevant Hydrofluoroolefin HFO-1234yf

Yun-Cheng Luo, Ming-Kuan Wang, Ling-Chao Yu, and Xingang Zhang*

Angew. Chem. Int. Ed. 2023, 62, e202308690


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104. Biocatalytic Fluoroalkylation Using Fluorinated S‑Adenosyl‑L‑methionine Cofactors

Wenping Ding, Minqi Zhou, Huayu Li, Miao Li, Yanping Qiu, Yu Yin, Lifeng Pan, Wenchao Yang, Yanan Du,* Xingang Zhang,* Zhijun Tang,* and Wen Liu*

Org. Lett. 202325 5650–5655

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103. Palladium-catalyzed highly selective gem-difluoroallylation of propargyl sulfonates with gem-difluoroallylboron

Hao-Wen Li, Yun-Cheng Luo, Ling-Chao Yu and Xingang Zhang*

Chem. Commun., 202359, 4241-4244.

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102. Synthesis of 1-(Trifluoromethyl)alkenes through Transition-Metal-Catalyzed Alkylation and Arylation of 1-Chloro-3,3,3-trifluoroprop-1-ene (HCFO-1233zd)

Wei Zhou, Qing-Wei Zhao, Yun-Cheng Luo, Xingang Zhang*

Synthesis 2023, 55, 1844–1854.


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101. Reductive Catalytic Difluorocarbene Transfer via Palladium Catalysis

Xue-Ying Zhang, Shi-Ping Sun, Yue-Qian Sang, Xiao-Song Xue, Qiao-Qiao Min, and Xingang Zhang*

Angew. Chem. Int. Ed. 2023, 62, e202306501

DOI: 10.1002/anie.202306501

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100. Copper-Catalyzed Difluorocarbene Transfer Enables Modular Synthesis

Xin Zeng, Yao Li, Qiao-Qiao Min, Xiao-Song Xue*, Xingang Zhang*

Nat. Chem. 2023, 15, 1064–1073

(Cover Story)



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