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81.trans-Selective Aryldifluoroalkylation of Endocyclic Enecarbamates and Enamides via Nickel Catalysis

Chang Xu, Ran Cheng, Yun-Cheng Luo, Ming-Kuan Wang, and Xingang Zhang*

Angew. Chem. Int. Ed. 2020, 59 , DOI:10.1002/anie.202008498


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80.Stereoselective Functionalization of Racemic Cyclopropylzinc Reagents via Enantiodivergent Relay Coupling

Lun An, Fei-Fei Tong, Shu Zhang and Xingang Zhang* 

J. Am. Chem. Soc. 2020, 142, 11884-11892

(Lun An and Fei-Fei Tong contributed equally.)


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79.Palladium Difluorocarbene Involved Catalytic Coupling with Terminal Alkynes

Xue-Ying Zhang, Xia-Ping Fu, Shu Zhang, Xingang Zhang*

CCS Chem. 2020, 2, 293–304.


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78.Nickel-Catalyzed Carbodifunctionalization of N-Vinylamides enables Access to γ-Amino Acids

Zhi-Fang Yanga , Chang Xub , Xing Zheng*, Xingang Zhang*

Chem. Commun, 2020, 56, 2642-2645

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77.Nickel-Catalyzed Carbonylation of Secondary Trifluoromethylated, Difluoromethylated, and Nonfluorinated Aliphatic Electrophiles with Arylboronic Acids under 1 atm of CO

Ran Cheng, Hai-Yang Zhao, Shu Zhang, and Xingang Zhang*

ACS Catal. 2020, 10, 36-42

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76.Copper-Catalyzed Highly Enantioselective Difluoroalkylation of Secondary Propargyl Sulfonates with Difluoroenoxysilanes

Xing Gao, Ran Cheng, Yu-Lan Xiao, Xiao-Long Wan, and Xingang Zhang*

Chem. 201952987-2999

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75.Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes

Xia-Ping Fu, Xiao-Song Xue, Xue-Ying Zhang, Yu-Lan Xiao, Shu Zhang, Yin-Long Guo, Xuebing Leng, 

Kendall N. Houk * and Xingang Zhang *

Nat. Chem. 2019, 11948956 

(A story behind this paper: )



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74.Nickel-Catalyzed Difluoroalkylation-Alkylation of Enamides 

Chang Xu, Zhi-Fang Yang, Lun An, and Xingang Zhang*,

ACS Catal. 2019, 9, 8224-8229


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73.Palladium-catalyzed cross-coupling of unactivated alkylzinc reagents with 2-bromo-3,3,3-trifluoropropene and its application in the synthesis of fluorinated amino acids

Yue-Guang Lou, An-Jun Wang, Liang Zhao, Lin-Feng He, Xiao-Fei Li, Chun-Yang He * and Xingang Zhang *

Chem. Commun. 2019, 55, 3705-3708

(This paper was highlighted by Chemical Synfacts, 2019, 55, 3705 )





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73. Nickel-Catalyzed Carbonylation of Difluoroalkyl Bromides with Arylboronic Acids 

Hai-Yang Zhao, Xing Gao, Shu Zhang, and Xingang Zhang* 

Org. Lett.201921, 1031–1036


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