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36. A
General Synthesis of Fluoroalkylated Alkenes by Palladium-Catalyzed Heck-Type
Reaction of Fluoroalkyl Bromides 
Zhang Feng, Qiao-Qiao Min, Hai-Yang Zhao, Ji-Wei
Gu and
Xingang Zhang*
Angew. Chem. Int. Ed. 2015, 54, 1270-1274
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35. Heteroaryldifluoromethylation of Organoborons Catalyzed by Palladium:
Facile Access to Aryl(Heteroaryl)difluoromethanes 
Yu-Lan Xiao, Bo Zhang, Zhang Feng, and Xingang
Zhang*
Org. Lett. 2014, 16, 4822−4825.
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34. Synthesis of α,α-Difluoromethylene Alkynes by Palladium-Catalyzed
gem-Difluoropropargylation of Aryl and Alkenyl Boron Reagents 
(This
paper was highlighted in Synfacts, 2014, 10, 1303 )
Yan-Bo Yu,
Guo-Zhen He and Xingang Zhang*
Angew. Chem. Int. Ed. 2014, 53, 10457 –10461
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33. Nickel-Catalyzed Cross-Coupling of Functionalized Difluoromethyl
Bromides and Chlorides with Aryl Boronic Acids: A General Method for
Difluoroalkylated Arenes
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25 )
Yu-Lan Xiao,Wen-Hao Guo, Guo-Zhen He, Qiang
Pan and Xingang
Zhang*.
Angew. Chem. Int. Ed. 2014, 53，9909-9913
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28. Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate
with iodo/bromo-aryl triazenes 
Zhang Feng, Yu-Lan Xiao and Xingang Zhang*
Org. Chem.
Front., 2014, 1, 113-116
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27. Palladium-Catalyzed
Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of
Aryldifluoromethylated Phosphonates and Carboxylic Acid
Derivatives 
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25  )
Zhang Feng, Qiao-Qiao Min, Yu-Lan Xiao, Bo Zhan and Xingang
Zhang*
Angew. Chem. Int. Ed. 2014, 53, 1669 –1673
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25. Highly Selective
gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes
Catalyzed by Palladium
Qiao-Qiao Min, Zengsheng Yin, Zhang Feng, Wen-Hao
Guo and Xingang Zhang*
J. Am. Chem. Soc.
2014, 136, 1230-1233
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16. Copper Catalyzed Cross-Coupling
of Iodobenzoates with Bromozinc-difluorophosphonate 
Zhang Feng
, Fei Chen , and Xingang Zhang *
Org.
Lett., 2012, 14, 1938-1941. (This paper was highlighted in Synfacts, 2012, 7, 0775  )
A DFT study of this reaction was reported by Jesús Jover (Organometallics 2018, 37, 327-336  )
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Copyright © 2012 Zhang Group, SIOC