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27. Palladium-Catalyzed
Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of
Aryldifluoromethylated Phosphonates and Carboxylic Acid
Derivatives 
(This paper was highlighted by Chemical
& Engineering News, 2014, 92,
25  )
Zhang Feng, Qiao-Qiao Min, Yu-Lan Xiao, Bo Zhan and Xingang
Zhang*
Angew. Chem. Int. Ed. 2014, 53, 1669 –1673
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26. Pd-catalyzed
cross-coupling of polyfluoroarenes with cyclic vinyl triflates 
YanBo Yu, Zhen Wang and Xingang Zhang*
Sci China
Chem, 2014, 57, 276-281
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25. Highly Selective
gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes
Catalyzed by Palladium
Qiao-Qiao Min, Zengsheng Yin, Zhang Feng, Wen-Hao
Guo and Xingang Zhang*
J. Am. Chem. Soc.
2014, 136, 1230-1233
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24. Thioether-Promoted Direct Olefination
of Polyfluoroarenes Catalyzed by Palladium
Cai-Zhi Wu, Chun-Yang He, Yangen Huang and
Xingang Zhang*
Org. Lett., 2013, 15, 5233-5269
(This
paper was highlighted in Synfacts, 2014,
10, 0062  )
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23. Pd-Catalyzed Direct Arylation of
Nitro-(pentafluorosulfanyl)benzenes with Aryl Bromides
Chao Wang, Yan-Bo Yu, Shilu Fan, and Xingang
Zhang*
Org. Lett., 2013, 15,
5004–5007
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22. Nickel-Catalyzed ortho-Selective
Hydrodefluorination of N-Containing Heterocycle-Polyfluoroarenes
Yi He, Zhao Chen, Chun-Yang He, Xingang
Zhang*
Chin. J. Chem. 2013, 31,
873—877
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21. Pd-Catalyzed Ortho-Selective C-F
Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially
Fluorinated Aromatics
Zhao Chen, Chun-Yang He, Zengsheng Yin, Yi
He and Xingang Zhang*
Angew. Chem. Int.
Ed. 2013, 52, 5813-5817
(This paper was highlighted in Synfacts, 2013,
8, 0878  )
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20. Pd-catalyzed oxidative cross-coupling
between two electron rich heteroarenes
Chun-Yang He, Zhen Wang, Cai-Zhi Wu, Feng-Ling
Qinga and Xingang Zhang*
Chem. Sci. 2013, 4, 3508-3513
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19. Construction of Optically Active
Quaternary Propargyl Amines by Highly Enantioselective Zinc/BINOL-Catalyzed
Alkynylation of Ketoimines
Gaochao Huang, Zengsheng Yin and Xingang
Zhang*
Chem. Eur.
J. 2013, 19, 11992-11998 (inside cover
paper)
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18. Copper- and Phosphine-Ligand-Free
Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes
with Allylic Chlorides
Yan-Bo Yu, Shilu Fan, and Xingang
Zhang*
Chem. Eur. J. 2012, 18, 14643-14648
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Copyright © 2012 Zhang Group, SIOC