75.Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes

Xia-Ping Fu, Xiao-Song Xue, Xue-Ying Zhang, Yu-Lan Xiao, Shu Zhang, Yin-Long Guo, Xuebing Leng, 

Kendall N. Houk ^* and Xingang Zhang ^*

Nat. Chem. 2019, 11, 948–956 

(A story behind this paper: )（after the paper）

74.Nickel-Catalyzed Difluoroalkylation-Alkylation of Enamides 

Chang Xu, Zhi-Fang Yang, Lun An, and Xingang Zhang*^,

^{ACS Catal. 2019, 9, 8224-8229}

73.Palladium-catalyzed cross-coupling of unactivated alkylzinc reagents with 2-bromo-3,3,3-trifluoropropene and its application in the synthesis of fluorinated amino acids

Yue-Guang Lou, An-Jun Wang, Liang Zhao, Lin-Feng He, Xiao-Fei Li, Chun-Yang He * and Xingang Zhang *

Chem. Commun. 2019, 55, 3705-3708

(This paper was highlighted by Chemical Synfacts, 2019, 55, 3705 )

72. Nickel-Catalyzed Carbonylation of Difluoroalkyl Bromides with Arylboronic Acids 

Hai-Yang Zhao, Xing Gao, Shu Zhang, and Xingang Zhang* 

Org. Lett., 2019, 21, 1031–1036

71.Nickel-Catalyzed Difluoromethylation of (Hetero)aryl Bromides with BrCF2H  

Xing Gao, Xu He and Xingang Zhang*

Chin. J. Org. Chem. 2019, 39, 215-222

(Invited paper, Dedicated to professor Qing-Yun Chen on the occasion of his 90th birthday )

70. Ni-Catalyzed Defluorination for the Synthesis of gem-Difluoro-1,3-dienes and Their [4+2] Cycloaddition Reaction  
 Minqi Zhou, Jian Zhang, Xing-Guo Zhang* and Xingang Zhang*

Org.Lett. 2019, 21, 671- 674

69. Fluoroalkylation-Borylation of Alkynes: An Efficient Method To Obtain (Z)‑Tri- and Tetrasubstituted Fluoroalkylated Alkenylboronates

Wen-Hao Guo, Hai-Yang Zhao, Zhi-Ji Luo, Shu Zhang, and Xingang Zhang*  

ACS Catal. 2019, 9, 38-43 

68. Iron-Catalyzed Cross-Coupling of Diarylzinc Reagents with gem-Difluoropropargyl Bromide    

An, Lun  Tong, Feifei  Zhang, Xingang*

Acta Chim. Sinica 2018, 76, 977—982 

(Invitated paper for Acta Chimica Sinica )

67. Palladium-catalyzed direct allylation of fluorinated benzothiadiazoles with allyl chlorides  

Jing Wang , Yan-Bo Yu , Xingang Zhang *

Tetrahedron. 2018, 74, 6329 - 6334. 

(Invitated paper for special issue on Organo Fluorine Chemistry )  

66. Nickel-Catalyzed Difluoroalkylation of (Hetero)aryl Bromides with Unactivated 1-Bromo-1,1-difluoroalkanes  

Xu He, Xing Gao, and Xingang Zhang*

Chin. J. Chem. 2018, 36, 1059－1062.

(Invited paper, Dedicated to professor Xiyan Lu on the occasion of his 90th birthday )