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70. Ni-Catalyzed
Defluorination for the Synthesis of gem-Difluoro-1,3-dienes
and Their [4+2] Cycloaddition Reaction 
Minqi Zhou, Jian Zhang, Xing-Guo Zhang* and Xingang
Zhang*
Org.Lett. 2019, 21, 671- 674
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69. Fluoroalkylation-Borylation of Alkynes: An Efficient Method To Obtain
(Z)‑Tri- and Tetrasubstituted Fluoroalkylated
Alkenylboronates
Wen-Hao Guo, Hai-Yang Zhao, Zhi-Ji Luo, Shu
Zhang, and Xingang Zhang*
ACS Catal. 2019, 9, 38-43
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68. Iron-Catalyzed
Cross-Coupling of Diarylzinc Reagents with gem-Difluoropropargyl Bromide
An, Lun Tong, Feifei Zhang, Xingang*
Acta Chim. Sinica 2018, 76, 977—982
(Invitated paper for Acta Chimica Sinica )
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67. Palladium-catalyzed direct allylation of fluorinated benzothiadiazoles
with allyl chlorides
Jing Wang , Yan-Bo Yu , Xingang Zhang *
Tetrahedron. 2018, 74, 6329 - 6334.
(Invitated paper for special issue on Organo Fluorine Chemistry )
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66. Nickel-Catalyzed Difluoroalkylation of (Hetero)aryl Bromides with Unactivated 1-Bromo-1,1-difluoroalkanes
Xu He, Xing Gao, and Xingang Zhang*
Chin. J. Chem. 2018, 36, 1059－1062.
(Invited paper, Dedicated to professor Xiyan Lu on the occasion of his 90th birthday )
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65. Transition-Metal
(Cu, Pd, Ni)-Catalyzed Difluoroalkylation via Cross-Coupling with Difluoroalkyl Halides 
Zhang Feng, Yu-Lan Xiao and Xingang Zhang*
Acc. Chem. Res., 2018, 51, 2264-2278
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64. Highly Selective
Pd-Catalyzed Direct C-F Bond Arylation of Simple Polyfluoroarenes 
Zhi-Ji Luo, Hai-Yang Zhao,
and Xingang Zhang*
Org. Lett., 2018, 20, 2543-2546
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63. A Bulky Diamine Ligand Promoted Cross-Coupling with Difluoroalkyl Bromides via Iron Catalysis
Lun An, Yu-Lan Xiao, Shu Zhang and Xingang Zhang*
Angew. Chem. Int. Ed. 2018, 57, 6921-6925
(This paper was highlighted by Synthfacts, 2018, 14, 0850  )
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62. Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
Chang Xu, Wen-Hao Guo, Xu He, Ying-Long Guo, Xue-Ying Zhang, and Xingang Zhang*
Nat. Commun., 2018, 9, 1170
(A story behind this paper:  )(This paper was chosen to feature within, under Fluorine for celebrating the International Year of the Periodic Table of Chemical Elements from across Nature and the Nature-branded journals)
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61. Bromotrifluoromethane: A Useful Reagent for
Hydrotrifluoromethylation of Alkenes and Alkynes
Yu-Yan Ren, Xing Zheng,* and Xingang Zhang*
Synlett, 2018, 29, 1028-1032
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