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64. Highly Selective
Pd-Catalyzed Direct C-F Bond Arylation of Simple Polyfluoroarenes 
Zhi-Ji Luo, Hai-Yang Zhao,
and Xingang Zhang*
Org. Lett., 2018, 20, 2543-2546
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63. A Bulky Diamine Ligand Promoted Cross-Coupling with Difluoroalkyl Bromides via Iron Catalysis
Lun An, Yu-Lan Xiao, Shu Zhang and Xingang Zhang*
Angew. Chem. Int. Ed. 2018, 57, 6921-6925
(This paper was highlighted by Synthfacts, 2018, 14, 0850  )
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62. Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
Chang Xu, Wen-Hao Guo, Xu He, Ying-Long Guo, Xue-Ying Zhang, and Xingang Zhang*
Nat. Commun., 2018, 9, 1170
(A story behind this paper:  )(This paper was chosen to feature within, under Fluorine for celebrating the International Year of the Periodic Table of Chemical Elements from across Nature and the Nature-branded journals)
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61. Bromotrifluoromethane: A Useful Reagent for
Hydrotrifluoromethylation of Alkenes and Alkynes
Yu-Yan Ren, Xing Zheng,* and Xingang Zhang*
Synlett, 2018, 29, 1028-1032
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60. Nickel-Catalyzed
Difluoromethylation of Arylboronic Acids with Bromodifluoromethane
Xia-Ping
Fu, Yu-Lan Xiao, and Xingang Zhang*
Chin. J. Chem., 2018, 36, 143-146
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59. Copper-Catalyzed Highly
Stereospecific Trifluoromethylation and Difluoroalkylation of Secondary
Propargyl Sulfonates 
Xing Gao, Yu-Lan Xiao,
Xiaolong Wan, and Xingang Zhang*
Angew. Chem. Int. Ed. 2018, 57, 3187-3191
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58. Palladium-Catalyzed Heck-Type Reaction of Secondary Trifluoromethylated Alkyl Bromides 
Tao Fan, Wei-Dong Meng and Xingang Zhang*
Beilstein J. Org. Chem. 2017, 13, 2610
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57. Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents 
Lun An, Chang Xu, and Xingang Zhang*
Nat. Commun. 2017, 8, 1460
(This paper was highlighted by Synform, 2018, 03, A36–A39)
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56.Synthesis of 5-pentafluorosulfanyl indazoles
Tao Fan, Wei-Dong Meng, Yu-Lan Xiao, Xingang Zhang*
Tetrahedron Letters 2017, 58, 4473
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55.Cholorodifluomethane-triggered formation of difluoromethylated arenes catalysed by paladium
Zhang Feng†, Qiao-Qiao Min†, Xia-Ping Fu†, Lun An and Xingang Zhang*
(†These authors contributed equally to this work)
(This paper was highlighted by Chemical & Engineering News, 2017, 95, 7 )
(This paper was highlighted by Molecule of the Week, 2017-06-19 )
(This paper was highlighted by Synthfacts, 2017, 9, 918 )
Nature Chem. 2017, 9, 918-923
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