50.Brønsted Acid Catalyzed gem-Difluoroallylation of Aldehydes with β-Tosyloxy-γ, γ-Difluroallylboronic Acid Pinacol Ester

Bo Zhang and Xingang Zhang*

 Chin. J. Chem. 2016, 34, 477-480

49.Copper-Catalyzed Direct Propargylation of Polyfluoroarene With Secondary Propargyl Phosphates

Yan-Bo Yu, Zhi-Ji Luo, and Xingang Zhang^*

Org.Lett. 2016,18, 3302-3305

48.Palladium-catalyzed phosphonyldifluoromethylation of alkenes with bromodifluoro-

methylphosphonate

Zhang Feng, Yu-Lan Xiao and Xingang Zhang*

Org. Chem. Front. 2016, 3, 466–469

47.Nickel-Catalyzed Difluoroalkylation of (Hetero)Arylborons with Unactivated 1-Bromo-1,1-difluoroalkanes 

Yu-Lan Xiao^†, Qiao-Qiao Min^†, Chang Xu, Ruo-Wen Wang and Xingang Zhang^*

(^†These authors contributed equally to this work)

Angew. Chem. Int. Ed. 2016, 55, 5837-5841

(This paper was highlighted in synfacts, 2016, 55, 5837-5841 )

46.Access to Difluoromethylated Arenes by Pd-Catalyzed Reaction of Arylboronic Acids with Bromodifluoroacetate 

Zhang Feng, Qiao-Qiao Min, and Xingang Zhang^*

^{Org. Lett. 2016, 18, 44-47}

45. Pd-Catalyzed gem-Difluoroallylation of Arylboronic Acids with γ, γ-Difluoroallylic Acetates 

Bo Zhang and Xingang Zhang*

Chem. Commun. 2016, 52, 1238-1241

44.Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides 

Xuefei Li, Zhang Feng, Zhong-Xing Jiang* and Xingang Zhang*

Org. Lett. 2015, 17, 5570-5573

43.Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives 

Ji-Wei Gu and Xingang Zhang*

Org. Lett., 2015, 17, 5384–5387

 (This paper was highlighted in Synfacts, 2016, 12, 242)

42.Palladium-Catalyzed Heck-Type Difluoroalkylation of Alkenes with Functionalized Difluoromethyl Bromides 

Feng Zhang, Qiao-Qiao Min, Xingang Zhang*

Synthesis. 2015, 47, 2912-2923 (Invited paper, Feature article)

41.Palladium-Catalyzed Direct Thienylation of Monobromide-Substituted Difluorinated Benzothiadiazoles for Organic Photovoltaics.

Qiang Pan, Chun-Yang He, Shiqing Han*, Xingang Zhang*

Synlett. 2015, 26, 2175-2179