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124.Difluoromethylene Cyclobutyl Sulfonium Salts: Versatile Reagents
for Chemodivergent Synthesis of Difluoroalkylated Cyclobutenes
and Cyclobutanes
Xiao-Tian Feng, Qiao-Qiao Min, Song-Yu Zhang, Hai-Yang Zhao, and Xingang Zhang*
Chemical Science, 2025, DOI: 10.1039/D5SC05409E
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123.A Bench-Stable Monofluoroallylsulfonium Salt for Highly Regioselective Monofluoroallylation
Ming-Xing Qu, Jian Zhang, Hai-Yang Zhao, and Xingang Zhang*
Eur. J. Org. Chem. 2025, 00, e202500625.
(invited paper for European Journal of Organic Chemistry)
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122.Ligand-Controlled Catalytic Diastereodivergent Hydro-gem-Difluoroallylation of Cyclopropenes
Wei Deng, Shasha Geng, Hai-Yang Zhao, and Xingang Zhang*
ACS Catal. 2025, 15, 14627−14638.
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121.Palladium(II) Difluorocarbene-Involved Catalytic Coupling with Benzyl/Allyl Electrophiles
Yi-Hao Xu, Shi-Ping Sun, Qiao-Qiao Min, and Xingang Zhang*
CCS Chem. 2025, 7, 1438–1448.
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120."Copper Difluorocarbene-Involved Catalytic gem-Difluoropropargylation"
Xin Zeng, Shi-Ping Sun, Hai-Yang Zhao, and Xingang Zhang*
Nat. Commun. 2025, 16, 4547
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119."[18F]Radiolabeling Fluorination of Monofluoroalkyl Triflates for the Synthesis of [18F] Difluoromethylated Alkanes"
Yuan-Zhan Han†, Peng-Fei Song†, Hai-Yang Zhao, Junbin Han*, Xingang Zhang*
Chem. Commun., 2025, 61, 7113 - 7116
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118."Nickel-Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β-Difluoroalkylated Amines
Fei-Fei Tong†, Xiao-Tian Feng†, Yuan-Zhan Han, Ming-Chen Huang, Hai-Yang Zhao, and Xingang Zhang*
Angew. Chem. Int. Ed. 2025, e202500990
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117."Synthesis of Difluoromethylene-Containing Compounds" In: Modern Strategies in Organofluorine Chemistry 1
Yun-Cheng Luo, Xingang Zhang*
Synthesis, 2024, 4, 370-398
(invited chapter for Science of Synthesis)
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116.Nickel-Catalyzed Difluoroalkylation of β,γ-Unsaturated α-Amino
Nitrile Derived Lithium Reagents
Fei-Fei Tong, Yun-Cheng Luo, Hai-Yang Zhao, Xia-Ping Fu, and Xingang Zhang*
Angew. Chem. Int. Ed. 2024, e202417858
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115.Transition-Metal-Mediated Fluoroalkylation of Carbon Electrophiles through Cross-Electrophile Couplings
Yun-Cheng Luo, Xingang Zhang*
Chin. J. Chem. 2024, 42, 3499—3517
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Copyright © 2012 Zhang Group, SIOC