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121."Copper Difluorocarbene-Involved Catalytic gem-Difluoropropargylation"
Xin Zeng, Shi-Ping Sun, Hai-Yang Zhao, and Xingang Zhang*
Nat. Commun. 2025, 16, 4547
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120."[18F]Radiolabeling Fluorination of Monofluoroalkyl Triflates for the Synthesis of [18F] Difluoromethylated Alkanes"
Yuan-Zhan Han†, Peng-Fei Song†, Hai-Yang Zhao, Junbin Han*, Xingang Zhang*
Chemical Communications, 2025, 61, 7113 - 7116
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119."Nickel-Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β-Difluoroalkylated Amines
Fei-Fei Tong†, Xiao-Tian Feng†, Yuan-Zhan Han, Ming-Chen Huang, Hai-Yang Zhao, and Xingang Zhang*
Angew. Chem. Int. Ed. 2025, e202500990
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118."Synthesis of Difluoromethylene-Containing Compounds" In: Modern Strategies in Organofluorine Chemistry 1
Yun-Cheng Luo, Xingang Zhang*
Science of Synthesis, 2024/4:; DOI: 10.1055/sos-SD-243-00012
(invited chapter for Science of Synthesis)
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117.Nickel-Catalyzed Difluoroalkylation of β,γ-Unsaturated α-Amino
Nitrile Derived Lithium Reagents
Fei-Fei Tong, Yun-Cheng Luo, Hai-Yang Zhao, Xia-Ping Fu, and Xingang Zhang*
Angew. Chem. Int. Ed. 2024, e202417858
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116.Transition-Metal-Mediated Fluoroalkylation of Carbon Electrophiles through Cross-Electrophile Couplings
Yun-Cheng Luo, Xingang Zhang*
Chin. J. Chem. 2024, 42, 3499—3517
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115.Difluorocarbene Enables Modular Synthesis of Difluoroalkylated Bicyclopentanes
Meng-Die Zhang, Hai-Yang Zhao, Xingang Zhang*
Eur. J. Org. Chem. 2024, e202400572
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114.Palladium(II)
Difluorocarbene-Involved Catalytic Coupling with Benzyl/Allyl Electrophiles
Yi-Hao Xu, Shi-Ping Sun, Qiao-Qiao Min, and
Xingang Zhang*
CCS Chem. 2025, 7, 1438–1448.
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113. Copper Difluorocarbene Enables Catalytic Difluoromethylation
Xin Zeng, Jimin Yang, Wei Deng, Xiao-Tian Feng, Hai-Yang Zhao, Lanfeng Wei, Xiao-Song Xue,* and Xingang Zhang*
J. Am. Chem. Soc. 2024, 146, 24, 16902-16911
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112. Site-Selective S-gem-Difluoroallylation of Unprotected Peptides with 3,3-Difluoroallyl Sulfonium Salts
Jin-Xiu Ren, Minqi Zhou, Xiao-Tian Feng, Hai-Yang Zhao, Xia-Ping Fu, and Xingang Zhang*
Chem. Sci., 2024, 15, 10002–10009
(Back Cover Story)
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