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92. Palladium-Catalyzed Carbonylative Cross-Coupling of Difluoroalkyl Halides with Alkylboranes under 1 atm of CO

Hai-Yang Zhao,§ Minqi Zhou,§ and Xingang Zhang*

Org. Lett. 2021, 23, 23, 9106-9111.


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91.Regio- and enantioselective umpolung gemdifluoroallylation of hydrazones via palladium catalysis enabled by N-heterocyclic carbene ligand

Shuai Huang, Fei-Fei Tong, Da-Chang Bai, Gao-Peng Zhang, Yang-Jie Jiang, Bo Zhang, Xuebing Leng, Ying-Long Guo, Xiao-Long Wan, Xingang Zhang*, Chang-Hua Ding* & Xue-Long Hou*

Nat. Commun., 202112, 6551.



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90.Visible-Light-Induced Palladium-Catalyzed Selective Defluoroarylation of Trifluoromethylarenes with Arylboronic Acids

Yun-Cheng Luo, Fei-Fei Tong, Yanxia Zhang, Chun-Yang He, and Xingang Zhang*

J. Am. Chem. Soc. 2021, 143, 13971-13979.

(This paper was highlighted by Synfacts, 2021, 17, 1230 

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89.Highly γ-Selective Arylation and Carbonylative Arylation of 3-Bromo-3,3-difluoropropene via Nickel Catalysis

Ran Cheng, Yueqian Sang, Xing Gao, Shu Zhang, Xiao-Song Xue*, and Xingang Zhang* 

Angew. Chem. Int. Ed. 202160, 12386-12391.

(Hot Paper)

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88Using Chlorotrifluoroethane for Tifluoroethylation of (Hetero)Aryl Bromides and Chlorides via Nickel Catalysis

Xuefei Li, Xing Gao, Chun-Yang He, Xingang Zhang*

Org. Lett. 2021, 23, 1400−1405.


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87Access to α,α-Difluoro-γ-amino Acids by Nickel-Catalyzed Reductive Aryldifluoroacetylation of N-Vinylacetamide

Qing-Wei Zhao, Zhi-Fang Yang, Xia-Ping Fu, Xingang Zhang*

Synlett 2021, 32, 1565-1569.

Invited paper for the Cluster Modern Nickel-Catalyzed Reactions

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