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21. Pd-Catalyzed Ortho-Selective C-F
Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially
Fluorinated Aromatics
Zhao Chen, Chun-Yang He, Zengsheng Yin, Yi
He and Xingang Zhang*
Angew. Chem. Int.
Ed. 2013, 52, 5813-5817
(This paper was highlighted in Synfacts, 2013,
8, 0878  )
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20. Pd-catalyzed oxidative cross-coupling
between two electron rich heteroarenes
Chun-Yang He, Zhen Wang, Cai-Zhi Wu, Feng-Ling
Qinga and Xingang Zhang*
Chem. Sci. 2013, 4, 3508-3513
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19. Construction of Optically Active
Quaternary Propargyl Amines by Highly Enantioselective Zinc/BINOL-Catalyzed
Alkynylation of Ketoimines
Gaochao Huang, Zengsheng Yin and Xingang
Zhang*
Chem. Eur.
J. 2013, 19, 11992-11998 (inside cover
paper)
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18. Copper- and Phosphine-Ligand-Free
Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes
with Allylic Chlorides
Yan-Bo Yu, Shilu Fan, and Xingang
Zhang*
Chem. Eur. J. 2012, 18, 14643-14648
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17. Copper-Catalyzed Dehydrogenative
Cross-Coupling of Benzothiazoles with Thiazoles and
Polyfluoroarene
Shilu Fan,
Zhao Chen, and Xingang Zhang*
Org.
Lett., 2012, 14, 4950–4953
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16. Copper Catalyzed Cross-Coupling
of Iodobenzoates with Bromozinc-difluorophosphonate 
Zhang Feng
, Fei Chen , and Xingang Zhang *
Org.
Lett., 2012, 14, 1938-1941. (This paper was highlighted in Synfacts, 2012, 7, 0775  )
A DFT study of this reaction was reported by Jesús Jover (Organometallics 2018, 37, 327-336  )
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15.
Pd-Catalyzed Dehydrogenative Cross-Coupling of Polyfluoroarenes with
Heteroatom-Substituted Enones
Fei Chen, Zhang Feng,
Chun-Yang He, Hao-Yang Wang, Yin-long Guo, and Xingang
Zhang*
Org. Lett. 2012, 14,
1176-1179
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14. Pd-Catalyzed
Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using
PPh3 Ligand
Fei Chen, Qiao-Qiao Min, and Xingang Zhang,*
J. Org. Chem. 2012, 77,2992-2998
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13. Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene-Thiophene Structure 
Chun-Yang He, Qiao-Qiao Min, and Xingang Zhang*
Organometallics 2012, 31, 1335-1340 (Invited paper in Special Issue: Fluorine in Organometallic Chemistry)
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12. Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl BoronicAcids with TMSCF3 and Elemental Sulfur 
Chao Chen, Yan Xie, Lingling Chu, Ruo-Wen Wang, Xingang Zhang, and Feng-Ling Qing*
Angew. Chem. Int. Ed. 2012, 51, 2492
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Copyright © 2012 Zhang Group, SIOC